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Effects of MgO-ZSM-23 Zeolite Catalyst on the Pyrolysis of PET Bottle Waste

Supak Tontisirin, Pattra Kongsupapkul, Kraipat Cheenkachorn

Abstract


The pyrolysis reaction of poly(ethylene terephthalate) or PET bottle waste was conducted comparatively in two cases: without catalyst and with MgO-ZSM-23 zeolite catalyst. The pyrolysis of PET was successfully decomposed to the product of liquid/wax, char, and gas (major product). Applying MgO-ZSM-23 catalyst, the product shows pronounced higher yield of gas (72.5 vs. 58.7 wt.%) and less yield of char solid (8 vs. 17.6 wt.%). The gas product shows less yield of CO2 (75 vs. 98 wt.%) but gives higher hydrocarbon gas fractions of C1–C5
(25 vs. 2.1 wt.%). In liquid/wax products, the catalytic pyrolysis shifted the product spectrum from higher molecular weight, e.g., biphenyl, terphenyl to benzene derivatives, predominantly in “benzoic acid”.


Keywords



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